ASTM C1219-92(1997)
Historical Standard: ASTM C1219-92(1997) Standard Test Methods for Arsenic in Uranium Hexafluoride
SUPERSEDED (see Active link, below)
ASTM C1219
1. Scope
1.1 These test methods are applicable to the determination of total arsenic in uranium hexafluoride (UF6) by atomic absorption spectrometry. Two test methods are given: Test Method A-Arsine Generation-Atomic Absorption (Sections 5 to 10), and Test Method B-Graphite Furnace Atomic Absorption (Sections 11 to 16).
1.2 The test methods are equivalent. The limit of detection for each test method is 0.1 [mu]g As/g U when using a sample containing 0.5 to 1.0 g U.
1.3 Test Method A covers the measurement of arsenic in uranyl fluoride (UO2F2) solutions by converting arsenic to arsine and measuring the arsine vapor by flame atomic absorption spectrometry.
1.4 Test Method B utilizes a solvent extraction to remove the uranium from the UO2F2 solution prior to measurement of the arsenic by graphite furnace atomic absorption spectrometry.
1.5 Both insoluble and soluble arsenic are measured when UF6 is prepared according to Test Method C761.
1.6 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
ASTM Standards
C761 Test Methods for Chemical, Mass Spectrometric, Spectrochemical, Nuclear, and Radiochemical Analysis of Uranium Hexafluoride
C787 Specification for Uranium Hexafluoride for Enrichment
D1193 Specification for Reagent Water
Keywords
arsenic; arsine; arsine generation; atomic absorption spectrometry; graphite furnace; uranium hexafluoride; uranyl fluoride; Zeeman background correction; Uranyl fluoride; Zeeman background correction; Arsenic content--nuclear materials/applications; Arsine generation; Atomic absorption spectrometry (AAS); Graphite furnace atomic absorption spectrometry (GFAAS); Nuclear fuels (reactor); Uranium hexafluoride (UF 6 )
ICS Code
ICS Number Code 27.120.30 (Fissile materials and nuclear fuel technology)
DOI: 10.1520/C1219-92R97
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