Already a subscriber?
MADCAD.com Free Trial
Sign up for a 3 day free trial to explore the MADCAD.com interface, PLUS access the
2009 International Building Code to see how it all works.
If you like to setup a quick demo, let us know at support@madcad.com
or +1 800.798.9296 and we will be happy to schedule a webinar for you.
Security check
Please login to your personal account to use this feature.
Please login to your authorized staff account to use this feature.
Are you sure you want to empty the cart?
BS EN 71-5:2013 Safety of toys - Chemical toys (sets) other than experimental sets, 2013
- Contents Page
- Foreword
- Introduction
- 1 Scope
- 2 Normative references
- 3 Terms and definitions
- 4 Plaster of Paris (gypsum) moulding sets [Go to Page]
- 4.1 Marking
- 4.2 First aid information
- 4.3 Safety rules
- 5 Ceramic and vitreous enamelling materials supplied in miniature workshop sets [Go to Page]
- 5.1 Chemical mixtures
- 5.2 Marking
- 5.3 First aid information
- 5.4 Safety rules
- 6 Oven-hardening plasticised PVC modelling clay sets [Go to Page]
- 6.1 Chemical substances
- 6.2 Marking
- 6.3 First aid information
- 6.4 Safety rules
- 7 Plastic moulding sets [Go to Page]
- 7.1 Polystyrene granules [Go to Page]
- 7.1.1 Chemical substances
- 7.1.2 Marking
- 7.1.3 First aid information
- 7.1.4 Safety rules
- 7.2 Embedding sets [Go to Page]
- 7.2.1 General
- 7.2.2 Packaging
- 7.2.3 Marking
- 7.2.4 First aid information
- 7.2.5 Safety rules
- 8 Adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents) supplied or recommended in model sets [Go to Page]
- 8.1 General
- 8.2 Adhesives [Go to Page]
- 8.2.1 Water-based adhesives [Go to Page]
- 8.2.1.1 General
- 8.2.1.2 Liquid adhesives for paper and wood
- 8.2.1.3 Adhesive sticks for paper
- 8.2.2 Solvent-based adhesives [Go to Page]
- 8.2.2.1 General
- 8.2.2.2 Multi-purpose adhesives
- 8.2.2.3 Contact adhesives
- 8.2.2.4 Special adhesives
- 8.2.2.5 Packaging
- 8.2.2.6 Marking
- 8.2.2.7 First aid information
- 8.2.2.8 Safety rules
- 8.3 Water-based paints and lacquers [Go to Page]
- 8.3.1 General
- 8.3.2 Packaging
- 8.3.3 Marking
- 8.3.4 First aid information
- 8.3.5 Safety rules
- 8.4 Solvent-based paints, lacquers, thinners and cleaning solvents [Go to Page]
- 8.4.1 General
- 8.4.2 Packaging
- 8.4.3 Marking
- 8.4.4 First aid information
- 8.4.5 Safety rules
- 9 Marking [Go to Page]
- 9.1 General
- 9.2 Marking of the primary packaging [Go to Page]
- 9.2.1 General
- 9.2.2 Manufacturer’s identification
- 9.2.3 Warning phrases
- 9.3 Marking of individual containers and any packagings
- 10 Instructions for use [Go to Page]
- 10.1 General
- 10.2 Contents list
- 10.3 Advice for adult supervision
- 10.4 Safety rules
- 10.5 Instructions for carrying out the activities
- 10.6 Spills and disposal of chemicals
- 11 Test methods [Go to Page]
- 11.1 General
- 11.2 Determination of elements in ceramic and vitreous enamelling materials [Go to Page]
- 11.2.1 Principle
- 11.2.2 Standards and reagents [Go to Page]
- 11.2.2.1 Standards
- 11.2.2.2 Reagents
- 11.2.3 Apparatus
- 11.2.4 Preparation of standard solutions [Go to Page]
- 11.2.4.1 Multi-element standard solution I
- 11.2.4.2 Multi-element standard solution II
- 11.2.4.3 Multi-element standard solution III
- 11.2.5 Blank solution
- 11.2.6 Sampling
- 11.2.7 Sample preparation
- 11.2.8 Procedure
- 11.2.9 Evaluation of results [Go to Page]
- 11.2.9.1 General
- 11.2.9.2 Calculation of the pigment contents in the enamel samples
- 11.2.10 Test report
- 11.3 Determination of plasticisers in oven-hardening polyvinyl chloride (PVC) modelling clay sets [Go to Page]
- 11.3.1 Principle
- 11.3.2 Standards and reagents [Go to Page]
- 11.3.2.1 Standards
- 11.3.2.2 Reagents
- 11.3.3 Apparatus
- 11.3.4 Preparation of standard solutions [Go to Page]
- 11.3.4.1 Stock solutions
- 11.3.4.2 Calibration solutions
- 11.3.4.3 Stability of standard solutions
- 11.3.5 Sampling
- 11.3.6 Sample preparation
- 11.3.7 Procedure [Go to Page]
- 11.3.7.1 Extraction of phthalic acid esters, citric acid esters and alkylsulfonic acid esters
- 11.3.7.2 Extraction of adipic acid polyesters
- 11.3.7.3 Evaporation of the solvent and weighing
- 11.3.7.4 Blank determination
- 11.3.7.5 GC-MSD determination of phthalic acid esters, citric acid esters and alkylsulfonic acid esters
- 11.3.7.6 ATR-FT-IR identification of adipic acid polyesters
- 11.3.8 Evaluation of results [Go to Page]
- 11.3.8.1 Calculation of solvent-extractable content containing plasticisers
- 11.3.8.2 Calculation and identification of plasticiser content by GC-MS analysis
- 11.3.9 Test report
- 11.4 Determination of the emission of benzene, toluene and xylenes from oven-hardening plasticised PVC modelling clay sets and plastic moulding sets [Go to Page]
- 11.4.1 Principle
- 11.4.2 Standards and reagents [Go to Page]
- Chemical
- CAS No.
- Toluene
- 108-88-3
- Benzene
- 71-43-2
- o-Xylene
- 95-47-6
- m-Xylene
- 108-38-3
- p-Xylene
- 106-42-3
- Chemical
- CAS No.
- Methanol
- 67-56-1
- 11.4.3 Apparatus
- 11.4.4 Preparation of standard solutions
- 11.4.5 Sampling
- 11.4.6 Sample preparation
- 11.4.7 Procedure
- 11.4.8 Evaluation of results
- 11.4.9 Test report
- 11.4.10 Critical control points
- 11.5 Determination of styrene content in polystyrene granules [Go to Page]
- 11.5.1 Principle
- 11.5.2 Standards and reagents [Go to Page]
- 11.5.2.1 Standards
- 11.5.2.2 Reagents
- 11.5.3 Apparatus
- 11.5.4 Preparation of the standard solutions
- 11.5.5 Sampling
- 11.5.6 Sample preparation
- 11.5.7 Procedure
- 11.5.8 Evaluation of results
- 11.5.9 Test report
- 11.6 Determination of organic solvents [Go to Page]
- 11.6.1 General
- 11.6.2 Principle
- 11.6.3 Standards and reagents [Go to Page]
- 11.6.3.1 Standards
- 11.6.3.2 Reagents
- 11.6.4 Apparatus
- 11.6.5 Preparation of the standard solutions [Go to Page]
- 11.6.5.1 Stock solutions for the identification and determination of solvents using HS-GC-FID
- 11.6.5.2 Stock solutions for the identification and determination of solvents using GC-MS
- 11.6.5.3 Stock solution for the identification and determination of propane-1,2-diol
- 11.6.5.4 Calibration solutions
- 11.6.6 Sampling
- 11.6.7 Sample preparation [Go to Page]
- 11.6.7.1 General
- 11.6.7.2 Sample preparation for identification and determination of solvents by HS-GC-FID
- 11.6.7.3 Sample preparation for identification of solvents by GC-MS
- 11.6.7.4 Sample preparation for determination of certain solvents by GC-MS
- 11.6.7.5 Sample preparation for determination of propane-1,2-diol using GC-FID
- 11.6.8 Procedure [Go to Page]
- 11.6.8.1 Identification of solvents using HS-GC-FID
- 11.6.8.2 Identification of solvents using GC-MS
- 11.6.8.3 Determination of solvent content by HS-GC-FID
- 11.6.8.4 Determination of solvent content using GC-MS
- 11.6.8.5 Determination of propane-1,2-diol by GC-FID
- 11.6.8.6 Blank determination
- 11.6.9 Evaluation of results [Go to Page]
- 11.6.9.1 Calculation of solvent content by HS-GC-FID
- 11.6.9.2 Calculation of solvent content by GC-MS or GC-FID
- 11.6.10 Test report
- 11.7 Combined approach for the determination of plasticisers in solvent-based adhesives and in solvent-based paints and lacquers, film-forming agents in paints and lacquers and modifiers in solvent-based paints and lacquers [Go to Page]
- 11.7.1 Principle
- 11.7.2 Determination of total extract [Go to Page]
- 11.7.2.1 Standards and reagents
- 11.7.2.2 Apparatus
- 11.7.2.3 Sampling
- 11.7.2.4 Sample preparation
- 11.7.2.5 Procedure
- 11.7.2.6 Evaluation of results
- 11.7.3 Identification of nitrocellulose [Go to Page]
- 11.7.3.1 Principle
- 11.7.3.2 Reagents
- 11.7.3.3 Apparatus
- 11.7.3.4 Sampling
- 11.7.3.5 Sample preparation
- 11.7.3.6 Procedure
- 11.7.3.7 Evaluation of results
- 11.7.4 Determination of plasticisers [Go to Page]
- 11.7.4.1 Principle
- 11.7.4.2 Standards and reagents
- 11.7.4.3 Apparatus
- 11.7.4.4 Preparation of the standard solution
- 11.7.4.5 Procedure
- 11.7.4.6 Evaluation of results
- 11.7.5 Determination of film-forming agents [Go to Page]
- 11.7.5.1 Principle
- 11.7.5.2 Standards and reagents
- 11.7.5.3 Apparatus
- 11.7.5.4 Preparation of standard solutions
- 11.7.5.5 Sampling
- 11.7.5.6 Procedure
- 11.7.5.7 Evaluation of results
- 11.7.6 Determination of the modifiers
- 11.7.7 Test report
- Annex A (normative)Environmental, health and safety precautions
- Annex B (informative)Organic solvents
- Annex C (informative)Maximum permitted element concentrations for the compounds permitted in ceramic and vitreous enamelling materials
- Annex D (informative)Validation of test methods
- Annex E (informative)Rationale [Go to Page]
- E.1 General remark
- E.2 Primary packaging (4.1; 5.2; 6.2; 7.1.2; 7.2.2; 8.2.1.2.2; 8.2.2.6; 8.3.2; 8.4.3; 9.2)
- E.3 Minimum age (4.1; 5.2; 6.2; 7.1.2; 7.2.3; 8.2.1.2.3; 8.2.1.3.3; 8.2.2.6; 8.3.3; 8.4.3)
- E.4 Phthalates (6.1 Table 2; 8.2.2; 8.4.1)
- E.5 Benzene (6.1, Table 3; 8.2.2.4, Table 12; 8.4.1, Table 16)
- E.6 Preservatives (7.2.1; 8.2.1.1; 8.3.1)
- Annex F (informative)Significant technical changes between this European Standard and the previous version
- Annex ZA (informative)Relationship between this European Standard and the Essential Requirements of EU Directive 2009/48/EC
- Bibliography [Go to Page]