ASTM D2010/D2010M-98(2004)
Historical Standard: ASTM D2010/D2010M-98(2004) Standard Test Methods for Evaluation of Total Sulfation Activity in the Atmosphere by the Lead Dioxide Technique
SUPERSEDED (see Active link, below)
ASTM D2010 / D2010M
1. Scope
1.1 These test methods describe the evaluation of the total sulfation activity in the atmosphere. Because of its oxidizing power, lead dioxide (PbO 2 ) converts not only sulfur dioxide (SO 2 ), but other compounds, such as mercaptans and hydrogen sulfide, into sulfate. It fixes sulfur trioxide and sulfuric acid mist present in the atmosphere (see Note 0).
1.2 Test Method A describes the use of a PbO 2 candle, and Test Method B describes that of a PbO 2 sulfation plate.
1.3 These test methods provide a weighted average effective SO 2 level for a 30-day interval.
1.4 The results of these test methods correlate approximately with volumetric SO 2 concentrations, although the presence of dew or condensed moisture tends to enhance the capture of SO 2 onto the candle or plate.
1.5 The values stated in SI units shall be regarded as the standard. The values given in brackets are for information only and may be approximate.
Note 0It has been shown that the rate constant of the chemical reaction between SO 2 and PbO 2 is independent of the concentration of SO 2 up to levels of 1000 ppm(v), if 15 % or less of the PbO 2 has been reduced () . 15 % of the PbO 2 is equivalent to 11 to 12 mg of SO 2 /cm 2 per day.
This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific precautionary statements, see Section .
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
ASTM Standards
D516 Test Method for Sulfate Ion in Water
D1193 Specification for Reagent Water
D1356 Terminology Relating to Sampling and Analysis of Atmospheres
D1357 Practice for Planning the Sampling of the Ambient Atmosphere
G91 Practice for Monitoring Atmospheric SO2 Deposition Rate for Atmospheric Corrosivity Evaluation
Keywords
atmospheres; Huey plates; lead dioxide; lead dioxide candles; sampling; sulfation; sulfation plates; sulfur dioxide; Atmospheric analysis; Gases (atmospheric); Lead dioxide technique; Specimen preparation (for testing)--atmospheric analysis; Sulfation (total); Sulfuric acid; Sulfur oxide gases; Total sulfation;
ICS Code
ICS Number Code 13.040.20 (Ambient atmospheres)
DOI: 10.1520/D2010_D2010M-98R04
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