Significance and Use

The measurement of particle-bound, oxidized, elemental, and total mercury in stationary-source flue gases provides data that can be used for dispersion modeling, deposition evaluation, human health and environmental impact assessments, emission reporting, compliance determinations, etc. Particle-bound, oxidized, and elemental mercury measurements before and after control devices may be necessary for optimizing and evaluating the mercury removal efficiency of emission control technologies.

1. Scope

1.1 This method applies to the determination of elemental, oxidized, particle-bound, and total mercury emissions from coal-fired stationary sources.

1.2 This method is applicable to elemental, oxidized, particle-bound, and total mercury concentrations ranging from approximately 0.5 to 100 ? g/Nm ³ .

1.3 This method describes equipment and procedures for obtaining samples from effluent ducts and stacks, equipment and procedures for laboratory analysis, and procedures for calculating results.

1.4 This method is applicable for sampling elemental, oxidized, and particle-bound mercury in flue gases of coal-fired stationary sources. It may not be suitable at all measurement locations, particularly those with high particulate loadings, as explained in Section 17.

1.5 Method applicability is limited to flue gas stream temperatures within the thermal stability range of the sampling probe and filter components.

1.6 The values stated in SI units are to be regarded as the standard. The values in parentheses are for information only.

1.7 This standard assumes users are familiar with EPA stack-gas sampling procedures as stated in EPA Methods 1 4, Method 5, and Method 17.

1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

ASTM Standards

D1193 Specification for Reagent Water

D1356 Terminology Relating to Sampling and Analysis of Atmospheres

D2986 Practice for Evaluation of Air Assay Media by the Monodisperse DOP (Dioctyl Phthalate) Smoke Test

D3154 Test Method for Average Velocity in a Duct (Pitot Tube Method)

D3685/D3685M Test Methods for Sampling and Determination of Particulate Matter in Stack Gases

E1 Specification for ASTM Liquid-in-Glass Thermometers

Keywords

air toxics; mercury; sampling; speciation; Air pollution/toxicity assessment; Coal-fired stationary source; Compliance testing; Deposits/deposition; Dispersion modeling; Elemental mercury; Emission monitoring; Environmental control/fate; Flue gas; Mercury; Ontario hydro method; Oxidized mercury; Particle-bound mercury; Sampling air/atmospheric materials/applications; Speciation; Total mercury;

ICS Code

ICS Number Code 13.040.40 (Stationary source emissions)

DOI: 10.1520/D6784-02R08

ASTM International is a member of CrossRef.

ASTM D6784